The stabilization of polyethylene with two-component stabilizing system

被引:2
作者
Lipinski, W
Ogonowski, J
Uhniat, M
机构
[1] Blachownia Heavy Organ Synth Inst, PL-47225 Kedzierzyn Kozle, Poland
[2] Cracow Univ Technol, PL-31155 Krakow, Poland
关键词
polyethylene; two-component stabilizing system; Irganox 1010; Ultranox 626; interaction synergism;
D O I
10.14314/polimery.2002.713
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The results of investigations of PE-LD stabilization with two-component system consisting of commercial stabilizers: "Irganox 1010" and "Ultranox 626" are presented. The effect of molar ratio of components on the system efficiency has been determined. Stabilizing system efficiency was estimated on the basis of induction time values (t(i)) of PE-LD oxidation process at temp. 210degreesC and 220degreesC. Induction time values have been determined from DTA measurements. On the basis of interaction coefficient (Theta) values calculated from equation (1) it has been found that the components of chosen stabilizing system show interaction synergism (Theta > 1) which significantly depends on molar ratio of the components. The optimal ratio is equal to 0.5.
引用
收藏
页码:713 / 716
页数:4
相关论文
共 21 条
[1]   AGING AND DEGRADATION OF POLYOLEFINS .3. POLYETHYLENE AND ETHYLENE-PROPYLENE COPOLYMERS [J].
DECKER, C ;
MAYO, FR ;
RICHARDSON, H .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1973, 11 (11) :2879-2898
[2]  
DECKER C, 1973, J POLYM SCI POL CHEM, V11, P2848
[3]  
HABICHER WD, 1997, MACR S, V115, P181
[4]  
HATEKAYAMA T, 1994, THERMAL ANAL
[5]   DTA FOR CONTROL OF STABILITY IN POLYOLEFIN WIRE AND CABLE COMPOUNDS [J].
HOWARD, JB .
POLYMER ENGINEERING AND SCIENCE, 1973, 13 (06) :429-434
[6]   USABILITY ANALYSIS OF A SIMPLIFIED KINETIC-EQUATION FOR EVALUATION OF ANTIOXIDANT ACTION IN LDPE [J].
LATOCHA, C ;
UHNIAT, M .
POLYMER DEGRADATION AND STABILITY, 1992, 35 (02) :115-120
[7]   TEMPERATURE EFFECT ON THE COOPERATIVE ACTION OF ANTIOXIDANTS [J].
LATOCHA, C ;
UHNIAT, M ;
BALCEROWIAK, W .
POLYMER DEGRADATION AND STABILITY, 1984, 7 (03) :189-192
[8]   INTERACTION OF THE THERMAL-DECOMPOSITION PRODUCTS OF AZODICARBONAMIDE WITH SOME ANTIOXIDANTS IN POLYETHYLENE [J].
LATOCHA, C ;
UHNIAT, M .
POLYMER DEGRADATION AND STABILITY, 1989, 23 (02) :193-199
[9]  
LATOCHA C, 1982, POLIMERY, V2, P67
[10]   MEASUREMENT OF OXIDATION STABILITY OF POLYOLEFINS BY THERMAL-ANALYSIS [J].
MARSHALL, DI ;
GEORGE, EJ ;
TURNIPSE.JM ;
GLENN, JL .
POLYMER ENGINEERING AND SCIENCE, 1973, 13 (06) :415-421