High turnover number of γ-SiW10{MnIII(OH2)}2O386- for oxygenation of cyclohexane with 1 atm molecular oxygen

被引：37

作者：

Hayashi, T ^{[1
]}

Kishida, A ^{[1
]}

Mizuno, N ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 05期

关键词：

D O I：

10.1039/a910334l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An all-inorganic oxo-bridged dimanganese-containing silicotungstate, gamma-SiW10{Mn-III(OH2)}(2)O-38(6-), showed the highest turnover number of 789 among various metal-substituted silicotungstates for the oxygenation of cyclohexane with 1 atm molecular oxygen; this is the highest level when compared with other catalysts reported so far.

引用

页码：381 / 382

页数：2

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