A chemistry and material perspective on lithium redox flow batteries towards high-density electrical energy storage

被引：471

作者：

Zhao, Yu ^{[1
,2
,3
]}

Ding, Yu ^{[1
,2
]}

Li, Yutao ^{[1
,2
]}

Peng, Lele ^{[1
,2
]}

Byon, Hye Ryung ^{[4
]}

Goodenough, John B. ^{[1
,2
]}

Yu, Guihua ^{[1
,2
]}

机构：

[1] Univ Texas Austin, Mat Sci & Engn Program, Austin, TX 78712 USA

[2] Univ Texas Austin, Dept Mech Engn, Austin, TX 78712 USA

[3] Soochow Univ, Inst Funct Nano & Soft Mat FUNSOM, Suzhou 215123, Jiangsu, Peoples R China

[4] RIKEN, Byon Initiat Res Unit IRU, Wako, Saitama 3510198, Japan

来源：

CHEMICAL SOCIETY REVIEWS | 2015年 / 44卷 / 22期

基金：

中国国家自然科学基金;

关键词：

MICROFLUIDIC FUEL-CELL; X-RAY-DIFFRACTION; LI-AIR BATTERIES; ELECTRODE MATERIALS; SULFUR BATTERIES; IN-SITU; RECHARGEABLE BATTERIES; POLYMER ELECTROLYTES; SOLID-ELECTROLYTE; ION CONDUCTIVITY;

D O I：

10.1039/c5cs00289c

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Electrical energy storage system such as secondary batteries is the principle power source for portable electronics, electric vehicles and stationary energy storage. As an emerging battery technology, Li-redox flow batteries inherit the advantageous features of modular design of conventional redox flow batteries and high voltage and energy efficiency of Li-ion batteries, showing great promise as efficient electrical energy storage system in transportation, commercial, and residential applications. The chemistry of lithium redox flow batteries with aqueous or non-aqueous electrolyte enables widened electrochemical potential window thus may provide much greater energy density and efficiency than conventional redox flow batteries based on proton chemistry. This Review summarizes the design rationale, fundamentals and characterization of Li-redox flow batteries from a chemistry and material perspective, with particular emphasis on the new chemistries and materials. The latest advances and associated challenges/opportunities are comprehensively discussed.

引用

页码：7968 / 7996

页数：29

共 280 条

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