Boroxine ring containing polymer electrolytes

被引:60
作者
Mehta, MA [1 ]
Fujinami, T
Inoue, T
机构
[1] Shizuoka Univ, Fac Engn, Dept Mat Sci, Hamamatsu, Shizuoka 4328561, Japan
[2] Genesis Res Inst, Nishi Ku, Nagoya, Aichi 4510051, Japan
关键词
polymer electrolyte; boroxine ring; ionic conductivity;
D O I
10.1016/S0378-7753(99)00151-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Anion trapping polymer electrolytes incorporating boroxine (B3O3) rings and oligoether side chains have been demonstrated to combine high Li+ ion transference numbers, thermal stability and an electrochemical stability window in the region of 4.9 V. Ionic conductivities of up to 1.6 X 10(-5) S cm(-1) at 30 degrees C and which exhibit Volger-Tamman-Fulcher (VTF) behaviour have been observed. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:724 / 728
页数:5
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