Allylation of alcohols and carboxylic acids with allyl acetate catalyzed by [Ir(cod)2]+BF4- complex

被引：37

作者：

Nakagawa, H

Hirabayashi, T

Sakaguchi, S

Ishii, Y ^{[1
]}

机构：

[1] Kansai Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5648680, Japan

[2] Kansai Univ, High Technol Res Ctr, Suita, Osaka 5648680, Japan

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2004年 / 69卷 / 10期

关键词：

D O I：

10.1021/jo049828k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A facile method for the synthesis of allyl alkyl ethers from alcohols with allyl acetate was developed by the use of [Ir(cod)(2)]+BF4- complex. For instance, the reaction of allyl acetate with n-octyl alcohol in the presence of a catalytic amount of [Ir(cod)(2)]+BF4- complex afforded allyl octyl ether in quantitative yield. Allyl carboxylates were also prepared by the exchange reaction between carboxylic acids and allyl acetate in good yields. The [Ir(cod)(2)]+BF4- complex catalyzed the reaction of alkyl and aromatic amines with allyl acetate to lead to the corresponding allylamines in fair to good yields.

引用

页码：3474 / 3477

页数：4

共 48 条

[1] The polymer incarcerated method for the preparation of highly active heterogeneous palladium catalysts [J].