New Insights into the Mechanism of Visible Light Photocatalysis

被引:588
作者
Banerjee, Swagata [1 ]
Pillai, Suresh C. [2 ,3 ]
Falaras, Polycarpos [4 ]
O'Shea, Kevin E. [5 ]
Byrne, John A. [6 ]
Dionysiou, Dionysios D. [7 ]
机构
[1] Dublin Inst Technol, FOCAS Inst, Ctr Res Engn Surface Technol, Dublin 8, Ireland
[2] Inst Technol Sligo, Dept Environm Sci, Sligo, Ireland
[3] Inst Technol Sligo, Ctr Precis Engn Mat & Mfg Res PEM, Sligo, Ireland
[4] NCSR Demokritos, Inst Adv Mat Physicochem Proc Nanotechnol & Micro, Athens 15310, Greece
[5] Florida Int Univ, Dept Chem & Biochem, Miami, FL 33199 USA
[6] Univ Ulster, Nanotechnol & Integrated Bioengn Ctr, Sch Engn, Fac Comp & Engn, Newtownabbey BT37 0QB, North Ireland
[7] Univ Cincinnati, Environm Engn & Sci Program, Sch Energy Environm Biol & Med Engn, Cincinnati, OH 45221 USA
来源
JOURNAL OF PHYSICAL CHEMISTRY LETTERS | 2014年 / 5卷 / 15期
基金
美国国家科学基金会; 爱尔兰科学基金会;
关键词
SENSITIZED SOLAR-CELLS; N-DOPED TIO2; TITANIUM-DIOXIDE; INDUCED DEGRADATION; ORGANIC POLLUTANTS; AEROBIC OXIDATION; GAS-PHASE; Z-SCHEME; WATER; FILMS;
D O I
10.1021/jz501030x
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In recent years, the area of developing visible-light-active photocatalysts based on titanium dioxide has been enormously investigated due to its wide range of applications in energy and environment related fields. Various strategies have been designed to efficiently utilize the solar radiation and to enhance the efficiency of photocatalytic processes. Building on the fundamental strategies to improve the visible light activity of TiO2-based photocatalysts, this Perspective aims to give an insight into many contemporary developments in the field of visible-light-active photocatalysis. Various examples of advanced TiO2 composites have been discussed in relation to their visible light induced photoconversion efficiency, dynamics of electron-hole separation, and decomposition of organic and inorganic pollutants, which suggest the critical need for further development of these types of materials for energy conversion and environmental remediation purposes.
引用
收藏
页码:2543 / 2554
页数:12
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