Oxidative addition of Ph3SnH to Pt3(μ-CO)3(PR3)3 (R = PCy3, PtBu3)

被引：5

作者：

Béni, Z ^{[1
]}

Scopelliti, R ^{[1
]}

Roulet, R ^{[1
]}

机构：

[1] Analyt Univ, Ecole Polytech Fed Lausanne, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 08期

关键词：

platinum clusters; tin; hydride; NMR; crystal structure; coordination compound;

D O I：

10.1016/j.inoche.2004.06.004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The oxidative addition of 1 equiv. of Ph3SnH to Pt-3(mu-CO)(3)(PCy3)(3) affords the triangular cluster [Pt-3(mu-CO)(3)(PCy3)(3)(Ph3Sn)H] (1). The same reaction with the isostructural 42-electron cluster [Pt-3(mu-CO)(3)(P'Bu-3)(3)] gives the 18-electron monomeric complex [PtH(CO)(P'Bu-3)(SnPh3) ] (2) instead of the 44-electron product. The structure of both complexes in solution have been established by H-1, C-13, P-31, Pt-195 and Sn-119 NMR spectroscopic methods and found to be in accordance with the solid state geometry of 1. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：935 / 937

页数：3

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