Reductive opening of aziridines with polymethylhydrosiloxane

被引：23

作者：

Chandrasekhar, S ^{[1
]}

Ahmed, M ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Hyderabad 500007, Andhra Pradesh, India

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 52期

关键词：

PMHS; aziridine opening; unusual amino acids;

D O I：

10.1016/S0040-4039(99)01974-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Regio and chemoselective reductive opening of aziridines is achieved using catalytic palladium on charcoal and polymethylhydrosiloxane (PMHS) as a soluble hydrogen source. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：9325 / 9327

页数：3

共 16 条

[1] Chemoselective reduction of carbonyl compounds with PMHS-ZnCl2 [J].

Chandrasekhar, S ;

Reddy, YR ;

Ramarao, C .

SYNTHETIC COMMUNICATIONS, 1997, 27 (13) :2251-2254

[2] Regioselective reductive ring opening of cyclic 1,2- and 1,3-benzylidene acetals [J].

Chandrasekhar, S ;

Reddy, YR ;

Reddy, CR .

CHEMISTRY LETTERS, 1998, (12) :1273-1274

[3] BIS(OXAZOLINE) COPPER-COMPLEXES AS CHIRAL CATALYSTS FOR THE ENANTIOSELECTIVE AZIRIDINATION OF OLEFINS [J].

EVANS, DA ;

FAUL, MM ;

BILODEAU, MT ;

ANDERSON, BA ;

BARNES, DM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (12) :5328-5329

[4] REDUCTIVE RING OPENINGS OF ALLYL-ALCOHOL EPOXIDES [J].

FINAN, JM ;

KISHI, Y .

TETRAHEDRON LETTERS, 1982, 23 (27) :2719-2722

[5]

GUIGEN L, 1996, ANGEW CHEM, V108, P451

[6] MITSUNOBU REACTIONS OF N-ALKYL AND N-ACYL SULFONAMIDES - AN EFFICIENT ROUTE TO PROTECTED AMINES [J].

HENRY, JR ;

MARCIN, LR ;

MCINTOSH, MC ;

SCOLA, PM ;

HARRIS, GD ;

WEINREB, SM .

TETRAHEDRON LETTERS, 1989, 30 (42) :5709-5712

[7] IMPROVEMENTS IN OSMIUM-CATALYZED OXYAMINATION OF OLEFINS BY CHLORAMINE-T [J].

HERRANZ, E ;

SHARPLESS, KB .

JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (12) :2544-2548

[8]

ILAN PB, 1986, J ORG CHEM, V51, P734

[9]

Kemp J. E. G., 1991, COMPREHENSIVE ORGANI, V7, P469, DOI DOI 10.1016/B978-0-08-052349-1.00199-2

[10] ASYMMETRIC COPPER-CATALYZED CYCLOPROPANATION OF TRISUBSTITUTED AND UNSYMMETRICAL CIS-1,2-DISUBSTITUTED OLEFINS - MODIFIED BIS-OXAZOLINE LIGANDS [J].

LOWENTHAL, RE ;

MASAMUNE, S .

TETRAHEDRON LETTERS, 1991, 32 (50) :7373-7376

← 1 2 →