Synthesis of a BEDT-TTF bipyridine organic donor and the first FeII coordination complex with a redox-active ligand

被引：52

作者：

Herve, Katel

Liu, Shi-Xia

Cador, Olivier

Golhen, Stephane

Le Gal, Yann

Bousseksou, Azzedine

Stoeckli-Evans, Helen

Decurtins, Silvio

Ouahab, Lahcene

机构：

[1] CNRS, UMR 6226, Equipe Organomet & Mat Mol, F-35042 Rennes, France

[2] Univ Bern, Dept Chem & Biochem, CH-3012 Bern, Switzerland

[3] CNRS, UPR 8241, Chim Coordinat Lab, F-31077 Toulouse, France

[4] Univ Neuchatel, Inst Chim, CH-2007 Neuchatel, Switzerland

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2006年 / 17期

关键词：

iron; N ligands; BEDT-TTF; synthesis design; redox chemistry;

D O I：

10.1002/ejic.200600351

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of the new ligand, BEDT-TTF-bipy [4,5-ethylenedithio-4',5'-(4'-methyl-2,2'-dipyrid-4-ylethylenedithio)-tetrathiafulvalene] is reported. The first Fe-II coordination complex, namely [Fe(NCS)(2)(BEDT-TTF-bipy)(2)]center dot CHCl3, with this redox-active ligand is obtained. Magnetic measurements and Mossbauer spectroscopy revealed the coexistence of high-spin and low-spin Fe-II species with a ratio of 40:60 in this compound. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

引用

页码：3498 / 3502

页数：5

共 40 条

[1] IMPROVED SYNTHESIS OF 4-VINYL-4'-METHYL-2,2'-BIPYRIDINE [J].