Comparison of Cyanide and Carbon Monoxide as Ligands in Iron(II) Porphyrinates

被引：34

作者：

Li, Jianfeng ^{[1
]}

Noll, Bruce C. ^{[1
]}

Schulz, Charles E. ^{[2
]}

Scheidt, W. Robert ^{[1
]}

机构：

[1] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA

[2] Knox Coll, Dept Phys, Galesburg, IL 61401 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 27期

基金：

美国国家卫生研究院;

关键词：

cyanides; iron; porphyrinoids; Mossbauer spectroscopy; structure elucidation; STRONG-FIELD LIGAND; LOW-SPIN; STRUCTURAL CHARACTERIZATION; ANIONIC COMPLEX; BINDING; STEREOCHEMISTRY; COORDINATION; HEMOGLOBIN; MOSSBAUER; INSIGHTS;

D O I：

10.1002/anie.200901434

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

cyanoporphyrinates, which are spin-crossover compounds, can be used to synthesize previously unknown sixcoordinate complexes. Bis(cyano) and (cyano)imidazole complexes are presented, and the five- and six-coordinate (cyano)iron(II) derivatives are compared with analogous CO complexes. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5010 / 5013

页数：4

共 36 条

[1]

[Anonymous], 2009, ANGEW CHEM, V121, P2676

[2] On hemochromogen. [J].

Anson, ML ;

Mirsky, AE .

JOURNAL OF GENERAL PHYSIOLOGY, 1928, 12 (02) :273-288

[3]

Antonini E., 1971, Hemoglobin and Myoglobin in. Their Reactions with Ligands

[4] STRUCTURAL CHARACTERIZATION OF LOW-SPIN IRON(III) COMPLEXES OF OCTAETHYLOXOPORPHYRIN [J].

BALCH, AL ;

NOLL, BC ;

SAFARI, N .

INORGANIC CHEMISTRY, 1993, 32 (13) :2901-2905

[5] A MOSSBAUER STUDY OF STRUCTURE AND BONDING IN IRON(II) LOW-SPIN COMPOUNDS [J].

BANCROFT, GM ;

MAYS, MJ ;

PRATER, BE .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (06) :956-&

[6] Crystal structure and molecular stereochemistry of the 1:2 adduct of anionic complex, dicyano-(5,10,15,20-tetramesityleneporphinato)-iron(II) with bis(triphenylphosphine)nitrogen (1+)•I2, CDCl3 solvate {[(CN)2FeII(TMP)][PPN]2}•I2•2CDCl3 [J].

Bartczak, TJ ;

Wolowiec, S ;

Latos-Grazynski, L .

INORGANICA CHIMICA ACTA, 1998, 277 (02) :242-246

[7] Stereochemistry of the Fe(II)- and Fe(III)-cyanide complexes of the homodimeric Scapharca inaequivalvis hemoglobin. A resonance Raman and FTIR study [J].

Boffi, A ;

Chiancone, E ;

Takahashi, S ;

Rousseau, DL .

BIOCHEMISTRY, 1997, 36 (15) :4505-4509

[8] Unusual affinity of cyanide for ferrous and ferric Scapharca inaequivalvis homodimeric hemoglobin. Equilibria and kinetics of the reaction [J].

Boffi, A ;

Ilari, A ;

Spagnuolo, C ;

Chiancone, E .

BIOCHEMISTRY, 1996, 35 (24) :8068-8074

[9] Dynamics of cyanide binding to ferrous Scapharca inaequivalvis homodimeric hemoglobin [J].

Boffi, A ;

Chiancone, E ;

Peterson, ES ;

Wang, JQ ;

Rousseau, DL ;

Friedman, JM .

BIOCHEMISTRY, 1997, 36 (15) :4510-4514

[10]

BRUNORI M, 1992, J BIOL CHEM, V267, P2258

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