Surface-anisotropic polystyrene spheres by electroless deposition

被引:65
作者
Cui, Jing-Qin [1 ]
Kretzschmar, Ilona [1 ]
机构
[1] CUNY City Coll, Dept Chem Engn, New York, NY 10031 USA
关键词
D O I
10.1021/la061742u
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Surfaces of sulfate-terminated polystyrene microspheres are anisotropically modified with silver nanoparticles covering 20-50% of the sphere surface using electroless deposition. A PDMS templating method is employed. Silver nanoparticles are found to deposit uniformly onto the exposed sphere surfaces. The deposition is diffusion-controlled and the nanoparticles adhere strongly to the polystyrene particles despite extensive exposure to ultrasonication. Silver content is confirmed by EDAX analysis. The final silver coverage is controlled via the PDMS pre-curing conditions.
引用
收藏
页码:8281 / 8284
页数:4
相关论文
共 27 条
[1]   Compression and structure of monolayers of charged latex particles at air/water and octane/water interfaces [J].
Aveyard, R ;
Clint, JH ;
Nees, D ;
Paunov, VN .
LANGMUIR, 2000, 16 (04) :1969-1979
[2]   Measurement of long-range repulsive forces between charged particles at an oil-water interface [J].
Aveyard, R ;
Binks, BP ;
Clint, JH ;
Fletcher, PDI ;
Horozov, TS ;
Neumann, B ;
Paunov, VN ;
Annesley, J ;
Botchway, SW ;
Nees, D ;
Parker, AW ;
Ward, AD ;
Burgess, AN .
PHYSICAL REVIEW LETTERS, 2002, 88 (24) :2461021-2461024
[3]   Metal-capped Brownian and magnetically modulated optical nanoprobes (MOONs): Micromechanics in chemical and biological microenvironments [J].
Behrend, CJ ;
Anker, JN ;
McNaughton, BH ;
Brasuel, M ;
Philbert, MA ;
Kopelman, R .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (29) :10408-10414
[4]  
BRANDRUP J, 1989, POLYM HDB
[5]  
Campbell DJ, 1999, J CHEM EDUC, V76, P537
[6]   Fabrication of asymmetrically coated colloid particles by microcontact printing techniques [J].
Cayre, O ;
Paunov, VN ;
Velev, OD .
JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (10) :2445-2450
[7]   Reduced symmetry metallodielectric nanoparticles: Chemical synthesis and plasmonic properties [J].
Charnay, C ;
Lee, A ;
Man, SQ ;
Moran, CE ;
Radloff, C ;
Bradley, RK ;
Halas, NJ .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (30) :7327-7333
[8]   Asymmetric functional colloids through selective hemisphere modification [J].
Correa-Duarte, MA ;
Salgueiriño-Maceira, V ;
Rodríguez-González, B ;
Liz-Marzán, LM ;
Kosiorek, A ;
Kandulski, W ;
Giersig, M .
ADVANCED MATERIALS, 2005, 17 (16) :2014-+
[9]  
Cui J., UNPUB
[10]   MECHANISM OF FORMATION OF 2-DIMENSIONAL CRYSTALS FROM LATEX-PARTICLES ON SUBSTRATES [J].
DENKOV, ND ;
VELEV, OD ;
KRALCHEVSKY, PA ;
IVANOV, IB ;
YOSHIMURA, H ;
NAGAYAMA, K .
LANGMUIR, 1992, 8 (12) :3183-3190