Oxidation of phosphines by supercritical nitrous oxide

被引：28

作者：

Poh, S ^{[1
]}

Hernandez, R ^{[1
]}

Inagaki, M ^{[1
]}

Jessop, PG ^{[1
]}

机构：

[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

来源：

ORGANIC LETTERS | 1999年 / 1卷 / 04期

关键词：

D O I：

10.1021/ol9906918

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Despite its reputation for lack of reactivity at moderate temperatures, nitrous oxide is capable of oxidizing at least one class of organic compounds, the phosphines, at temperatures at or below 100 degrees C. The use of supercritical N2O as both the solvent and the reactant simplifies the isolation of the products and allows one to avoid the use of flammable liquid solvents.

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收藏

页码：583 / 585

页数：3

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