Effect of Carbon Matrix Dimensions on the Electrochemical Properties of Na3V2(PO4)3 Nanograins for High-Performance Symmetric Sodium-Ion Batteries

被引:500
作者
Li, Shuo [1 ]
Dong, Yifan [1 ]
Xu, Lin [1 ,2 ]
Xu, Xu [1 ]
He, Liang [1 ]
Mai, Liqiang [1 ]
机构
[1] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, WUT Harvard Joint Nano Key Lab, Wuhan 430070, Peoples R China
[2] Harvard Univ, Dept Chem & Chem Biol, Cambridge, MA 02138 USA
基金
中国国家自然科学基金; 对外科技合作项目(国际科技项目);
关键词
ELECTRICAL ENERGY-STORAGE; LITHIUM BATTERIES; LONG-LIFE; NA; CATHODE; CHALLENGES; INSERTION; ANODE; ELECTROLYTE; COMPOSITE;
D O I
10.1002/adma.201305522
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Na3V2(PO4)(3) nanograins dispersed in different carbon matrices are rationally synthesized and systematically characterized. The acetylene carbon matrix provides the best conductive networks for electrons and sodium ions, which endows Na3V2(PO4)(3) stable cyclability and high rate performance. The Na3V2(PO4)(3)-based symmetric sodium-ion batteries show outstanding electrochemical performance, which is promising for large-scale and low-cost energy storage applications.
引用
收藏
页码:3545 / 3553
页数:9
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