Direct simulation of non-equilibrium kinetics under shock conditions in nitrogen

被引：46

作者：

Bruno, D ^{[1
]}

Capitelli, M ^{[1
]}

Esposito, F ^{[1
]}

Longo, S ^{[1
]}

Minelli, P ^{[1
]}

机构：

[1] Univ Bari, Dipartimento Chim, CNR, Ist Metodol Inorgan & Plasmi,Sez Bari, I-70126 Bari, Italy

来源：

CHEMICAL PHYSICS LETTERS | 2002年 / 360卷 / 1-2期

关键词：

D O I：

10.1016/S0009-2614(02)00772-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We study the interplay of vibrational kinetics, dissociation, translational and rotational relaxation in a strong shock wave in nitrogen by Direct Simulation Monte Carlo simulation (DSMC). The input data for vibrational and chemical processes are all in the form of cross-sections, mostly determined by molecular physics methods. In particular, we use for the first time very recent Quasi-Classical Trajectory (QCT) results for cross-sections of multi-quantum VT energy exchange and dissociation in N + N-2 collisions. Non-equilibrium distributions are observed and discussed. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：31 / 37

页数：7

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