Complete study of the pyrolysis and gasification of scrap tires in a pilot plant reactor

被引:113
作者
Conesa, JA [1 ]
Martín-Gullón, I [1 ]
Font, R [1 ]
Jauhiainen, J [1 ]
机构
[1] Univ Alicante, Dept Chem Engn, E-03080 Alicante, Spain
关键词
D O I
10.1021/es034608u
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The pyrolysis and gasification of tires was studied in a pilot plant reactor provided with a system for condensation of semivolatile matter. The study comprises experiments at 450, 750, and 1000 degreesC both in nitrogen and 10% oxygen atmospheres. Analysis of all the products obtained (gases, liquids, char, and soot) are presented. In the gas phase only methane and benzene yields increase with temperature until 1000 degreesC. In the liquids the main components are styrene, limonene, and isoprene. The solid fraction (including soot) increases with temperature. Zinc content of the char decreases with increasing temperature.
引用
收藏
页码:3189 / 3194
页数:6
相关论文
共 15 条
[1]   THE DEGRADATION OF GUAYULE RUBBER AND THE EFFECT OF RESIN COMPONENTS ON DEGRADATION AT HIGH-TEMPERATURE [J].
BHOWMICK, AK ;
RAMPALLI, S ;
GALLAGHER, K ;
SEEGER, R ;
MCINTYRE, D .
JOURNAL OF APPLIED POLYMER SCIENCE, 1987, 33 (04) :1125-1139
[2]   EFFECT OF HEATING RATE ON THERMAL-DEGRADATION OF POLYBUTADIENE [J].
BRAZIER, DW ;
SCHWARTZ, NV .
JOURNAL OF APPLIED POLYMER SCIENCE, 1978, 22 (01) :113-124
[3]  
Bridgwater AV, 1989, PYROLYSIS GASIFICATI, P209
[4]   POLYMER REACTIONS .10. THERMAL PYROLYSIS OF POLY(ISOPRENE) [J].
CHIEN, JCW ;
KIANG, JKY .
EUROPEAN POLYMER JOURNAL, 1979, 15 (11) :1059-1065
[5]   Kinetic model for the combustion of tyre wastes [J].
Conesa, JA ;
Font, R ;
Fullana, A ;
Caballero, JA .
FUEL, 1998, 77 (13) :1469-1475
[6]   Mass spectrometry validation of a kinetic model for the thermal decomposition of tyre wastes [J].
Conesa, JA ;
Font, R ;
Marcilla, A .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1997, 43 (01) :83-96
[7]   Gas from the pyrolysis of scrap tires in a fluidized bed reactor [J].
Conesa, JA ;
Font, R ;
Marcilla, A .
ENERGY & FUELS, 1996, 10 (01) :134-140
[8]   Tire pyrolysis: Evolution of volatile and semivolatile compounds [J].
Conesa, JA ;
Fullana, A ;
Font, R .
ENERGY & FUELS, 2000, 14 (02) :409-418
[9]   EVOLVED GAS-ANALYSIS OF PYROLYSIS PRODUCTS FROM SOME RUBBERS BY MASS-SPECTROMETRY [J].
ERDOGAN, M ;
YALCIN, T ;
TINCER, T ;
SUZER, S .
EUROPEAN POLYMER JOURNAL, 1991, 27 (4-5) :413-417
[10]   Evolution of products in the combustion of scrap tires in a horizontal, laboratory scale reactor [J].
Fullana, A ;
Font, R ;
Conesa, JA ;
Blasco, P .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2000, 34 (11) :2092-2099