Performance of polymer electrolyte membrane fuel cell (PEMFC) stacks Part I. Evaluation and simulation of an air-breathing PEMFC stack

被引:140
作者
Chu, D [1 ]
Jiang, RZ [1 ]
机构
[1] USA, Res Lab, Sensor & Elect Devices Directorate, Adelphi, MD 20783 USA
关键词
fuel cell; PEMFC; fuel cell stack; PEMFC stack; portable power source; electrode kinetics;
D O I
10.1016/S0378-7753(99)00285-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 [物理化学]; 081704 [应用化学];
摘要
The performance of an ah-breathing polymer electrolyte membrane fuel cell (PEMFC) stack was evaluated under different environmental conditions. The humidity of the surrounding air significantly affected the performance of the stack. When the humidity was less than 10% RH at 35 degrees C, the stack lost almost 95% power. Acceptable operating temperature for the stack would be from 20 to 40 degrees C for > 36% RN. An empirical equation was proposed to analyze the performance of the PEMFC stack instead of only for a single cell. The results calculated with the empirical equation are: excellently fitted to the experimental polarization curves at various humidity and temperatures. The impedance and Tafel slope of the stack both increase with decreasing either the environmental humidity or temperature. Published by Elsevier Science S.A.
引用
收藏
页码:128 / 133
页数:6
相关论文
共 13 条
[1]
Electrocatalysis, diffusion and ohmic drop in PEMFC: Particle size and spatial discrete distribution effects [J].
Antoine, O ;
Bultel, Y ;
Durand, R ;
Ozil, P .
ELECTROCHIMICA ACTA, 1998, 43 (24) :3681-3691
[2]
Effect of Nafion dispersion on the stability of Pt/WO3 electrodes [J].
Chen, KY ;
Tseung, ACC .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (09) :2703-2707
[3]
CHEN PK, 1996, J ELECTROCHEM SOC, V142, pL85
[4]
O2 reduction at the Pt/Nafion interface in 85% concentrated H3PO4 [J].
Chu, D .
ELECTROCHIMICA ACTA, 1998, 43 (24) :3711-3718
[5]
High-performance, low Pt content catalysts for the electroreduction of oxygen in polymer-electrolyte fuel cells [J].
Fournier, J ;
Faubert, G ;
Tilquin, JY ;
Cote, R ;
Guay, D ;
Dodelet, JP .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (01) :145-154
[6]
FULLER TF, 1997, ELECTROCHEMICAL FAL, P26
[7]
MODELING OF PROTON-EXCHANGE MEMBRANE FUEL-CELL PERFORMANCE WITH AN EMPIRICAL-EQUATION [J].
KIM, J ;
LEE, SM ;
SRINIVASAN, S ;
CHAMBERLIN, CE .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (08) :2670-2674
[8]
Low-cost light weight high power density PEM fuel cell stack [J].
Murphy, OJ ;
Cisar, A ;
Clarke, E .
ELECTROCHIMICA ACTA, 1998, 43 (24) :3829-3840
[9]
Influence of the structure in low-Pt loading electrodes for polymer electrolyte fuel cells [J].
Passalacqua, E ;
Lufrano, F ;
Squadrito, G ;
Patti, A ;
Giorgi, L .
ELECTROCHIMICA ACTA, 1998, 43 (24) :3665-3673
[10]
MASS-TRANSPORT PHENOMENA IN PROTON-EXCHANGE MEMBRANE FUEL-CELLS USING O2/HE, O2/AR, AND O2/N2 MIXTURES .1. EXPERIMENTAL-ANALYSIS [J].
RHO, YW ;
VELEV, OA ;
SRINIVASAN, S ;
KHO, YT .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (08) :2084-2088