Fast-Sintered Gehlenite Glass-Ceramics from Plasma-Vitrified Municipal Solid Waste Incinerator Fly Ashes

被引:50
作者
Bernardo, Enrico [1 ]
Scarinci, Giovanni [1 ]
Edme, Erika [2 ]
Michon, Ulysse [2 ]
Planty, Nicholas [2 ]
机构
[1] Univ Padua, Dipartimento Ingn Meccan Settore Mat, I-35131 Padua, Italy
[2] EUROPLASMA, F-33100 Bordeaux, France
关键词
VITRIFICATION; CRYSTALLIZATION; COMPOSITES; IMMOBILIZATION; PRODUCTS;
D O I
10.1111/j.1551-2916.2008.02892.x
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
081705 [工业催化]; 082905 [生物质能源与材料];
摘要
Plasma heating is a highly efficient industrial treatment for municipal solid waste incinerator fly ashes, converted into leach-resistant glass. The viscous flow sintering of glass powders appears a very promising way for the subsequent conversion of the vitrified waste, not refined and available as glass flakes, into valuable glass-ceramics. Because of the particular glass composition, the densification of glass-ceramics was much hindered by the strong tendency of glass toward surface crystallization. The crystallization of glass was successfully coupled to a low porosity, thus yielding strong gehlenite-based glass-ceramics (with a bending strength exceeding 100 MPa), by adopting a fast sintering treatment (direct insertion of glass compacts at 1050 degrees C, with an holding time of 1 h).
引用
收藏
页码:528 / 530
页数:3
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