Relative distributions of phenol dimers and hydroxy acids in a cultivated soil and above ground maize tissue

被引:23
作者
Dignac, Marie-France [1 ]
Rumpel, Cornelia [1 ]
机构
[1] Univ Paris 06, INRA, UMR, Lab Biogeochim & Ecol Milieux Continentaux BioEMC, F-78850 Thiverval Grignon, France
关键词
D O I
10.1016/j.orggeochem.2006.06.019
中图分类号
P3 [地球物理学]; P59 [地球化学];
学科分类号
0708 ; 070902 ;
摘要
The distributions of lignin-derived phenol dimers and cutin/suberin-derived hydroxy carboxylic acids were studied in a single analysis using CuO oxidation of maize leaves and stems as well as the plough layer of a silty soil cultivated with maize. Their relative contributions in soils and plants were compared to that of lignin monomers reported in a previous study. The x,16-dihydroxyhexadecanoic acid isomers and 9,10,18-trihydroxyoctadecanoic acid were the most abundant hydroxy acids in the soil. An x-hydroxy hexadecane-1,16-dioic acid was relatively enriched in soil compared to maize leaves. Hydroxy acids were relatively enriched in soils compared to lignin-derived phenols. Lignin dimers were relatively enriched in soil with regard to lignin monomers. Lignin dimers with 5,5 aryl-aryl and a,2-methyl linkages were the most concentrated dimers in soil compared to the plant tissue. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1634 / 1638
页数:5
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