Ring-opening polymerization of 3,6-dimethyl-2,5-morpholinedione with discrete amino-alkoxy-bis(phenolate) yttrium initiators: mechanistic insights

被引：22

作者：

Castro, Pascal M. ^{[1
]}

Zhao, Gang ^{[1
]}

Amgoune, Abderramane ^{[1
]}

Thomas, Christophe M. ^{[1
]}

Carpentier, Jean-Francois ^{[1
]}

机构：

[1] Univ Rennes 1, Lab Organomet & Catalyse, UMR 6226, F-35042 Rennes, France

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 43期

关键词：

D O I：

10.1039/b612580h

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

Alkoxy-amino-bis(phenolate) yttrium amide and alkoxide complexes promote the ring-opening polymerization of (3S, 6S)-dimethyl-2,5-morpholinedione at 60 - 100 degrees C via a coordination - insertion polymerization mechanism.

引用

页码：4509 / 4511

页数：3

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