A cylindrical cavity with two different hydrogen-binding boundaries:: the calix[4]arene skeleton screwed onto the meso-positions of the calix[4]pyrrole

被引:77
作者
Bonomo, L
Solari, E
Toraman, G
Scopelliti, R
Latronico, M
Floriani, C [1 ]
机构
[1] Univ Lausanne, BCH, Inst Chim Minerale & Analyt, CH-1015 Lausanne, Switzerland
[2] Univ Basilicata, Dipartimento Ingn & Fis Ambiente, I-85100 Potenza, Italy
关键词
D O I
10.1039/a907563a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The acid-catalyzed condensation of pyrrole with p- or m-hydroxyacetophenone led to the formation of meso-tetramethyltetrakis(hydroxyphenyl)calix[4]pyrroles occurring in three isomeric forms, with the cone conformer displaying topologically variable multi-site or multi-point surfaces for binding neutral or anionic substrates.
引用
收藏
页码:2413 / 2414
页数:2
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