Syntheses and characterization of ZnII and CdII coordination polymers, [Zn(μ-bpe)(NO2)2]n and [Cd2([μ-bpp)3(NO2)4]n

被引：5

作者：

Amiri, Maryam Ghoreishi

Ranjbar, Zohreh Rashidi

Morsali, Ali ^{[1
]}

Yilmaz, Veysel T.

Buyukgungor, Orhan

机构：

[1] Tarbiat Modares Univ, Dept Chem, Sch Sci, Tehran, Iran

[2] Ondokuz Mayis Univ, Fac Arts & Sci, Dept Chem, Kurupelit, Samsun, Turkey

[3] Ondokuz Mayis Univ, Fac Arts & Sci, Dept Phys, Kurupelit, Samsun, Turkey

来源：

SOLID STATE SCIENCES | 2006年 / 8卷 / 09期

关键词：

zinc; cadmium; trans-1,2-bis(4-pyridyl)ethene; 1,3-di(4-pyridyl)propane; coordination polymers;

D O I：

10.1016/j.solidstatesciences.2006.03.007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new Zn-II and Cd-II coordination polymers of trans-1,2-bis(4-pyridyl)ethene (bpe) and 1,3-di(4-pyridyl)propane (bpp) with anionic nitrite ligands, [Zn(mu-bpe)(NO2)(2)](n) (1) and [Cd-2(mu-bPP)(3)(NO2)(4)](n) (2) have been synthesized and characterized by elemental analysis, IR-, H-1 NMR-and C-13 NMR spectroscopy and studied by X-ray crystallography. The structural studies of (1) and (2) show the compounds are one- and three-dimensional polymers with coordination environments of distorted octahedral and pentagonal bipyramide, ZnN2O4 and CdN3O4, respectively. Self-assembly of these compounds in the solid state via pi-pi-stacking interactions is discussed. (c) 2006 Elsevier SAS. All rights reserved.

引用

页码：1115 / 1120

页数：6

共 23 条

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