Lipase-catalysed synthesis of biosurfactants by transacylation of N-methyl-glucamine and fatty-acid methyl esters.

被引：17

作者：

Maugard, T ^{[1
]}

RemaudSimeon, M ^{[1
]}

Petre, D ^{[1
]}

Monsan, P ^{[1
]}

机构：

[1] RHONE POULENC RECH,SERV CATALYSE,F-69192 ST FONS,FRANCE

来源：

TETRAHEDRON | 1997年 / 53卷 / 22期

关键词：

D O I：

10.1016/S0040-4020(97)00458-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学]; 081704 [应用化学];

摘要：

The enzymatic synthesis of a range of amide surfactants by transesterification reactions between various amines and fatty-acid methyl esters (Diester(R)) a low-cost natural and renewable raw material is described. The transacylation reaction catalysed by a commercial lipase from Candida antarctica (Novozym(R)) at 90 degrees C, yielded 100% conversion of fatty-acid methyl esters with 80% amide synthesis in less than 20 hours. Yield and chemoselectivity of the reaction are under the control of the fatty-acid methyl ester/amine molar ratio. (C) 1997 Elsevier Science Ltd.

引用

页码：7629 / 7634

页数：6

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