Kinetic Analysis of Solid-State Reactions: A General Empirical Kinetic Model

被引:62
作者
Cai, Junmeng [1 ]
Liu, Ronghou [1 ]
机构
[1] Shanghai Jiao Tong Univ, Sch Agr & Biol, Biomass Energy Engn Res Ctr, Shanghai 200240, Peoples R China
基金
中国国家自然科学基金;
关键词
ACTIVATION-ENERGY; HETEROGENEOUS REACTIONS;
D O I
10.1021/ie8018615
中图分类号
TQ [化学工业];
学科分类号
081705 [工业催化];
摘要
In this research note, we presented a general empirical kinetic model that can fit any ideal kinetic model and even deviations produced by heterogeneities in particle shapes. The algebraic expression of the general empirical kinetic model is f(alpha) = alpha(m) (1 - q alpha)(n). The kinetic model can be used for performing the kinetic analysis of experimental data without previous assumptions about the form of the reaction kinetic model. The empirical kinetic model has been evaluated from the theoretical and experimental data.
引用
收藏
页码:3249 / 3253
页数:5
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