Performance and lifetime analysis of the kW-class PEMFC stack

被引:87
作者
Ahn, SY
Shin, SJ
Ha, HY
Hong, SA
Lee, YC
Lim, TW
Oh, IH [1 ]
机构
[1] Korea Inst Sci & Technol, Fuel Cell Res Ctr, Seoul 136791, South Korea
[2] Sungkyunkwan Univ, Dept Chem Engn, Suwon 440746, South Korea
[3] Hyundai Motor Co, Fuel Cell Vehicle Team, Namyang 445850, South Korea
关键词
proton exchange membrane fuel cell (PEMFC); stack; lifetime analysis;
D O I
10.1016/S0378-7753(01)01032-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 [物理化学]; 081704 [应用化学];
摘要
A counter-now type 40-cell proton exchange membrane fuel cell (PEMFC) stack with an effective electrode area of 200 cm 2 has been assembled and its performance was investigated. Under the condition of atmospheric pressure and 75 degreesC, the maximum power of the stack was 2.89 kW (0.36 W/cm(2) per cell) and 2.3 kW (0.29 W/cm(2) per cell) for H-2/O-2 and H-2/Air, respectively. However, the stack showed a rapid decay in performance after continuous operation of 1800 h. Electron probe micro analyzer (EPMA) and X-ray fluorescence (XRF) spectrometer analyses revealed that degradation of the catalyst and contamination of the polymer electrolyte membrane were the main causes of such sudden decay. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:295 / 303
页数:9
相关论文
共 11 条
[1]
AHN SY, 1999, THEOR APPL CHEM ENG, V5, P3393
[2]
Barbir F., 1996, FUEL CELL. 1996 Fuel Cell Seminar. Program and Abstracts, P505
[3]
BLOMEN LJM, 1993, FUEL CELL SYSTEM
[4]
Bockris J.O., 1969, Fuel Cells: Their electrochemistry
[5]
CHOI HJ, 2000, HWAHAK KONGHAK, V38, P550
[6]
CHUN YG, 1999, THEOR APPL CHEM ENG, V5, P3389
[7]
GULZOW E, 2000, FUEL CELL SEM ABSTR, P156
[8]
KO YT, 1996, DEV 1 KW CLASS PEMFC
[9]
KORDESCH K, 1996, FUEL CELL THEIR APPL
[10]
Maeda H., 1996, FUEL CELL. 1996 Fuel Cell Seminar. Program and Abstracts, P272