Needle-like apatite-leucite glass-ceramic as a base material for the veneering of metal restorations in dentistry

被引:62
作者
Höland, W [1 ]
Rheinberger, V [1 ]
Wegner, S [1 ]
Frank, M [1 ]
机构
[1] Ivoclar Ltd, FL-9494 Schaan, Liechtenstein
关键词
Polymer; Precipitation; Crystallization; Optical Property; Apatite;
D O I
10.1023/A:1008977416834
中图分类号
R318 [生物医学工程];
学科分类号
0831 [生物医学工程];
摘要
A needle-like apatite-leucite glass-ceramic was prepared in the SiO2-Al2O3-Na2O-K2O-P2O5-F system. Nucleation and crystallization processes were studied in bulk and powdered samples. The crystallization of leucite follows the mechanism of surface crystallization. After the precipitation of NaCaPO4 crystals and another unknown crystal phase, the formation of needle-like apatite is based on a volume nucleation and crystallization process. The mechanism of the formation of needle-like apatite differs to those of apatite precipitation in glass-ceramics. The morphology of needle-like apatite is comparable to that of apatite in natural teeth. The properties of the glass-ceramic, especially the good chemical durability, the optical properties, as well as mechanical and thermal properties allow glass-ceramic to be used as a main component in a bio-material for the veneering of metal restorations in dentistry. (C) 2000 Kluwer Academic Publishers.
引用
收藏
页码:11 / 17
页数:7
相关论文
共 23 条
[1]
[Anonymous], 1978, OUTLINE DENT MAT AND
[2]
STRUCTURE OF THE LOW-TEMPERATURE VARIETY OF CALCIUM SODIUM ORTHO-PHOSPHATE, NACAPO4 [J].
BENAMARA, M ;
VLASSE, M ;
LEFLEM, G ;
HAGENMULLER, P .
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1983, 39 (NOV) :1483-1485
[3]
*BRIT STAND, 1978, 5612 BS
[4]
APATITE MULLITE GLASS-CERAMICS [J].
HILL, R ;
WOOD, D .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 1995, 6 (06) :311-318
[5]
Biocompatible and bioactive glass-ceramics - state of the art and new directions [J].
Holand, W .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1997, 219 :192-197
[6]
SURFACE CRYSTALLIZATION OF LEUCITE IN GLASSES [J].
HOLAND, W ;
FRANK, M ;
RHEINBERGER, V .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1995, 180 (2-3) :292-307
[7]
HOLAND W, 1992, CELL MATER, V2, P105
[8]
Holand W., 1996, PHOSPHOROUS RES B, V6, P111
[9]
HOLAND W, 1998, UNPUB J NONCRYST SOL
[10]
Holand W., 1995, BIOCERAMICS, V8, P299