Synthesis of novel rhodium-carbene complexes as efficient catalysts for addition of phenylboronic acid to aldehydes

被引：40

作者：

Özdemir, I ^{[1
]}

Demir, S

Çetinkaya, B

机构：

[1] Inonu Univ, Dept Chem, TR-44069 Malatya, Turkey

[2] Ege Univ, Dept Chem, TR-35100 Izmir, Turkey

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2004年 / 215卷 / 1-2期

关键词：

N-heterocyclic carbene; rhodium complexes; imidazolidinylidine; arylation; aldehydes;

D O I：

10.1016/j.molcata.2003.12.037

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Rhodium(I)-carbene complexes with 1,3-dialkylimidazolidin-2-ylidine ligand were prepared and characterized by conventional spectroscopic methods and elemental analyses. The rhodium-carbene complexes RhCl(COD)(1,3-dialkyl-imidazolinylidene), 2a-d, are an active catalyst for addition of phenylboronic acid to aldehydes. (C) 2004 Elsevier B.V. All rights reserved.

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页码：45 / 48

页数：4

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