Proton elimination in charge-separation reactions with hydrogen halides driven by chemical-bond formation with triply-charged C-60 cations

被引：9

作者：

Baranov, V ^{[1
]}

Bohme, DK ^{[1
]}

机构：

[1] YORK UNIV,CTR RES EARTH & SPACE SCI,N YORK,ON M3J 1P3,CANADA

来源：

CHEMICAL PHYSICS LETTERS | 1996年 / 258卷 / 1-2期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/0009-2614(96)00642-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Experimental results are reported which demonstrate the efficient elimination of protons in charge-separation reactions of C-60(.3+) with HCl and HBr at room temperature. Two mechanisms are observed for the production of protons in these ion/molecule reactions: dissociative electron transfer and halide transfer with concomitant chemical-bond formation. Both occur in the reaction with HBr which produces protons in all reactive collisions.

引用

页码：203 / 206

页数：4

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