A New Visible Light Sensitive Photoinitiator System for the Cationic Polymerization of Epoxides

被引：104

作者：

Crivello, James V. ^{[1
]}

机构：

[1] Rensselaer Polytech Inst, Dept Chem & Chem Biol, Troy, NY 12180 USA

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2009年 / 47卷 / 03期

关键词：

cationic polymerization; initiators; irradiation; photopolymerization; ring-opening polymerization; BENZOINE DERIVATIVES; PHOTOPOLYMERIZATION; DIARYLIODONIUM; SALT; OXIDE;

D O I：

10.1002/pola.23203

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This communication reports the development of an efficient three-component visible light sensitive photoinitiator system for the cationic ring-opening photo-polymerization of epoxide monomers and epoxide functional oligomers. The photoinitiator system consists of camphorquinone in combination with a benzyl alcohol to generate free radicals by the absorption of visible light. Subsequently, the radicals participate in the free radical chain induced decomposition of a diaryliodonium salt. The resulting strong Bronsted acid derived from this process catalyzes the cationic ring-opening polymerization of a variety of epoxide substrates. (C) 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 866-875, 2009

引用

页码：866 / 875

页数：10

共 33 条

[1]

Aydogan B., 2006, RES SIGNPOSTS, P187

[2]

AYLETT BJ, 1979, ORGANOMETALLIC COMPO, V1, P104

[3] LIGHT-INDUCED POLYMER AND POLYMERIZATION REACTIONS .17. CATIONIC PHOTOPOLYMERIZATION OF ISOBUTYLGLYCIDYL ETHER WITH BENZOINE DERIVATIVES ARYLONIUM-SALTS-INITIATOR OR BENZYLDIMETHYL KETAL ARYLONIUM-SALTS-INITIATOR SYSTEMS [J].

BAUMANN, H ;

TIMPE, HJ .

JOURNAL FUR PRAKTISCHE CHEMIE, 1984, 326 (04) :529-536

[4]

BAUMANN H, 1984, Z CHEM, V24, P18

[5]

Crivello J. V., 2003, POLYM MAT SCI ENG PR, V88, P209

[6]

Crivello J.V., 1993, RING OPENING POLYM, P157

[7] Effect of temperature on the cationic photopolymerization of epoxides [J].

Crivello, James V. .

JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2008, 45 (08) :591-598

[8] Synergistic effects in hybrid free radical/cationic photopolymerizations [J].

Crivello, James V. .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2007, 45 (16) :3759-3769

[9] Cationic photopolymerization of alkyl glycidyl ethers [J].

Crivello, JV .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2006, 44 (09) :3036-3052

[10] Curcumin: A naturally occurring long-wavelength photosensitizer for diaryliodonium salts [J].

Crivello, JV ;

Bulut, U .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2005, 43 (21) :5217-5231

← 1 2 3 4 →