A short, enantiospecific synthesis of a protected seco acid precursor to (R,R)-(-)-pyrenophorin

被引：14

作者：

Hoffman, RV

Patonay, T

Nayyar, NK

Tao, JH

机构：

[1] Dept. of Chemistry and Biochemistry, New Mexico State University, Las Cruces

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 14期

关键词：

D O I：

10.1016/0040-4039(96)00323-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Described herein is a four-step enantiospecific synthesis of a protected seco acid precursor of (R,R)-(-)-pyrenophorin in 23% yield from a chiral beta-ketoester 3, which can be prepared in one step from ethyl acetoacetate by a standard procedure. Copyright (C) 1996 Elsevier Science Ltd

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页码：2381 / 2384

页数：4

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