Chirality induction on achiral N-methyl aromatic amide oligomers bearing terminal carboxy groups with chiral Amines

被引：20

作者：

Nishimura, T ^{[1
]}

Maeda, K ^{[1
]}

Yashima, E ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Engn, Dept Mol Design & Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan

来源：

CHIRALITY | 2004年 / 16卷

关键词：

N-methyl aromatic amide; induced circular dichroism; acid-base; optically active; absolute configuration; chiral discrimination;

D O I：

10.1002/chir.20028

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

Novel unsymmetrical N-methyl aromatic amide oligomers bearing two carboxy groups at both ends were synthesized and their complexation with various optically active amines in solution was investigated using circular dichroism (CD) spectroscopy. The complexes showed a characteristic induced CD in the absorption region due to the aromatic amide reflecting the absolute configuration of the chiral amines. (C) 2004 Wiley-Liss, Inc.

引用

页码：S12 / S22

页数：11

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