Polyphophazene containing indole-based dual chromophores: Synthesis and nonlinear optical characterization

被引：101

作者：

Li, Z

Qin, JG ^{[1
]}

Li, SJ

Ye, C

Luo, J

Cao, Y

机构：

[1] Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China

[2] Chinese Acad Sci, Ctr Mol Sci, Organ Solids Lab, Inst Chem, Beijing 100080, Peoples R China

[3] S China Univ Technol, Coll Mat Sci, Guangzhou 510640, Peoples R China

来源：

MACROMOLECULES | 2002年 / 35卷 / 24期

关键词：

D O I：

10.1021/ma020769r

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A two-step method to develop polyphophazenes containing the indole-based chromophores was presented. A polyphophazene with indole as side chains was first synthesized and then the post-azo coupling of p-nitrobenzenediazonium fluoroborate toward the indole ring afforded a multifunctional indole-based chromophore functionalized polyphophazene. The polymer exhibited excellent solubility in common organic solvents.

引用

收藏

页码：9232 / 9235

页数：4

相关论文

共 23 条

[1] SYNTHESIS OF POLY(ORGANOPHOSPHAZENES) WITH GLYCOLIC ACID ESTER AND LACTIC-ACID ESTER SIDE-GROUPS - PROTOTYPES FOR NEW BIOERODIBLE POLYMERS [J].

ALLCOCK, HR ;

PUCHER, SR ;

SCOPELIANOS, AG .

MACROMOLECULES, 1994, 27 (01) :1-4

[2] Synthesis and characterization of hindered polyphosphazenes via functionalized intermediates: Exploratory models for electro-optical materials [J].

Allcock, HR ;

Ravikiran, R ;

Olshavsky, MA .

MACROMOLECULES, 1998, 31 (16) :5206-5214

[3] 2ND-ORDER NONLINEAR OPTICAL POLY(ORGANOPHOSPHAZENES) - SYNTHESIS AND NONLINEAR OPTICAL CHARACTERIZATION [J].

ALLCOCK, HR ;

DEMBEK, AA ;

KIM, C ;

DEVINE, RLS ;

SHI, YQ ;

STEIER, WH ;

SPANGLER, CW .

MACROMOLECULES, 1991, 24 (05) :1000-1010

[4] SYNTHESIS OF HIGH POLYMERIC ALKOXY- AND ARYLOXPHOSPHONITRILES [J].

ALLCOCK, HR ;

KUGEL, RL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (18) :4216-&

[5] Molecular motion of phosphazene-bound nonlinear optical chromophores [J].

Allcock, HR ;

Cameron, CG ;

Skloss, TW ;

TaylorMeyers, S ;

Haw, JF .

MACROMOLECULES, 1996, 29 (01) :233-238

[6] INORGANIC-ORGANIC POLYMERS [J].

ALLCOCK, HR .

ADVANCED MATERIALS, 1994, 6 (02) :106-115

[7] LIQUID-CRYSTALLINE PHOSPHAZENES BEARING BIPHENYL MESOGENIC GROUPS [J].

ALLCOCK, HR ;

KIM, C .

MACROMOLECULES, 1990, 23 (17) :3881-3887

[8]

Dalton L. R., 1995, Nonlinear Optics, Principles, Materials, Phenomena and Devices, V10, P383

[9] Low Tg photorefractive polyacrylate containing 3-(6-nitrobenzoxazol-2-yl)indole a a monolithic chromophore [J].

Hwang, J ;

Sohn, J ;

Lee, JK ;

Lee, JH ;

Chang, JS ;

Lee, GJ ;

Park, SY .

MACROMOLECULES, 2001, 34 (13) :4656-4658

[10] A LIQUID-CRYSTALLINE POLY(ORGANOPHOSPHAZENE) [J].

KIM, C ;

ALLCOCK, HR .

MACROMOLECULES, 1987, 20 (07) :1726-1727