Immobilization of Rh(PPh3)3Cl on phosphinated MCM-41 for catalytic hydrogenation of olefins

被引：118

作者：

Shyu, SG ^{[1
]}

Cheng, SW ^{[1
]}

Tzou, DL ^{[1
]}

机构：

[1] Acad Sinica, Inst Chem, Taipei, Taiwan

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 23期

关键词：

D O I：

10.1039/a907207a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complex Rh(PPh3)(3)Cl immobilized on MCM-41 modified with (OEt)(3)Si(CH2)(3)PPh2 results in a stable hydrogenation catalyst with turnover frequency (TOF) three times higher than that of Rh(PPh3)(3)Cl in the hydrogenation of cyclohexene.

引用

页码：2337 / 2338

页数：2

共 16 条

[1] SUPPORTED TRANSITION-METAL COMPLEXES .2. SILICA AS SUPPORT
ALLUM, KG
HANCOCK, RD
HOWELL, IV
MCKENZIE, S
PITKETHLY, RC
ROBINSON, PJ
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 87 (02) : 203 - 216
[2] SUPPORTED TRANSITION-METAL COMPLEXES .1. ORGANIC POLYMERS AS SUPPORT
ALLUM, KG
HANCOCK, RD
HOWELL, IV
PITKETHLY, RC
ROBINSON, PJ
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 87 (02) : 189 - 201
[3] SUPPORTED TRANSITION-METAL COMPLEXES .5. LIQUID-PHASE CATALYTIC-HYDROGENATION OF HEXENE-1, CYCLOHEXENE AND ISOPRENE UNDER CONTINUOUS-FLOW CONDITIONS
ALLUM, KG
HANCOCK, RD
HOWELL, IV
LESTER, TE
MCKENZIE, S
PITKETHLY, RC
ROBINSON, PJ
[J]. JOURNAL OF CATALYSIS, 1976, 43 (1-3) : 331 - 338
[4] SUPPORTED TRANSITION-METAL COMPLEXES .4. RHODIUM CATALYSTS FOR LIQUID-PHASE HYDROFORMYLATION OF HEXENE-1
ALLUM, KG
HANCOCK, RD
HOWELL, IV
PITKETHLY, RC
ROBINSON, PJ
[J]. JOURNAL OF CATALYSIS, 1976, 43 (1-3) : 322 - 330
[5] A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES
BECK, JS
VARTULI, JC
ROTH, WJ
LEONOWICZ, ME
KRESGE, CT
SCHMITT, KD
CHU, CTW
OLSON, DH
SHEPPARD, EW
MCCULLEN, SB
HIGGINS, JB
SCHLENKER, JL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) : 10834 - 10843
[6] Optimal parameters for the synthesis of the mesoporous molecular sieve [Si]-MCM-41
Cheng, CF
Park, DH
Klinowski, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1997, 93 (01): : 193 - 197
[7] Functionalized monolayers on ordered mesoporous supports
Feng, X
Fryxell, GE
Wang, LQ
Kim, AY
Liu, J
Kemner, KM
[J]. SCIENCE, 1997, 276 (5314) : 923 - 926
[8] CATALYTIC REDUCTION OF OLEFINS WITH A POLYMER-SUPPORTED RHODIUM(I) CATALYST
GRUBBS, RH
KROLL, LC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (12) : 3062 - &
[9] Iwasawa Y., 1986, TAILORED METAL CATAL
[10] HYDROGENATION OF OLEFINS BY SUPPORTED TRANSITION-METAL COMPLEXES
KOCHLOEFL, K
LIEBELT, W
KNOZINGER, H
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1977, (15) : 510 - 511

← 1 2 →