Synthesis and Reactivity of a Mono-σ-Aryl Palladium(IV) Fluoride Complex

被引：233

作者：

Ball, Nicholas D. ^{[1
]}

Sanford, Melanie S. ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 11期

关键词：

FORMING REDUCTIVE ELIMINATION; FLUORINATION; PD(II); CHEMISTRY; DYNAMICS; HALIDES; BONDS; XENON;

D O I：

10.1021/ja8054595

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This communication describes the rational design and synthesis of the remarkably stable Pd-IV monoaryl fluoride complex (t-Bu-bpy)Pd-IV(p-FC6H4)(F)(2)(FHF) (t-Bu-bpy 4,4'-di-tert-butyl-2,2'-bipyridine). This and related complexes undergo Ar-F bond formation in the presence of "F+" sources. This work serves as a foundation for the development of Pd-II/IV-catatyzed coupling reactions to form aryl fluorides.

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页码：3796 / +

页数：3

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