The first coordination compound containing three different types of spin carriers:: 2p-3d-4f (TCNQ•-, Cu2+ and Gd3+)

被引:119
作者
Madalan, AM
Roesky, HW
Andruh, M
Noltemeyer, M
Stanica, N
机构
[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany
[2] Univ Bucharest, Fac Chem, Inorgan Chem Lab, Bucharest 70254, Romania
[3] Romanian Acad, Inst Phys Chem, Coordinat Chem Lab, Bucharest, Romania
关键词
D O I
10.1039/b202628g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel heterospin system, [{CuL}(2)Gd(TCNQ)(2)].TCNQ- .CH3OH.2CH(3)CN, is obtained by reacting the mononuclear complex, [CuL], with gadolinium(III) nitrate, followed by the substitution of the nitrato ions with anionic organic radicals.
引用
收藏
页码:1638 / 1639
页数:2
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