Color Tunability and Electrochemiluminescence of Silver Nanoclusters

被引:436
作者
Diez, Isabel
Pusa, Matti [1 ]
Kulmala, Sakari [1 ]
Jiang, Hua [2 ]
Walther, Andreas [3 ]
Goldmann, Anja S. [3 ]
Muller, Axel H. E. [3 ]
Ikkala, Olli
Ras, Robin H. A. [1 ]
机构
[1] Helsinki Univ Technol, Analyt Chem Lab, FIN-02150 Espoo, Finland
[2] Helsinki Univ Technol, Nanomat Grp, FIN-02150 Espoo, Finland
[3] Bayreuther Zentrum Kolloide & Grenzflachen, Bayreuth, Germany
关键词
electrochemiluminescence; nanostructures; quantum dots; silver; solvatochromism; METAL NANOPARTICLES; AQUEOUS-SOLUTION; AG NANOCLUSTERS; FLUORESCENT; CHAINS; ACID);
D O I
10.1002/anie.200806210
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
(Graph Presented) Colorful clusters: Silver nanoclusters consisting of only a few atoms exhibit large chemical-environment-responsive shifts of their optical absorption and emission bands, that is, large solvatochromism (see picture). The photophysical characteristics and electrochemiluminescence of the Ag clusters give them remarkable advantages over larger nanoparticles in applications such as molecular sensing. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:2122 / 2125
页数:4
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