Defect photoluminescence in polycrystalline diamond films grown by arc-jet chemical-vapor deposition

被引:11
作者
Lal, S [1 ]
Dallas, T [1 ]
Yi, S [1 ]
Gangopadhyay, S [1 ]
Holtz, M [1 ]
Anderson, FG [1 ]
机构
[1] UNIV VERMONT,DEPT PHYS,BURLINGTON,VT 05405
来源
PHYSICAL REVIEW B | 1996年 / 54卷 / 19期
关键词
D O I
10.1103/PhysRevB.54.13428
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We have studied a series of sharp photoluminescence emission lines between 1.65 and 1.80 eV in synthetic diamond films. The series of lines is decomposed into a set of parent lines plus vibrational sidebands spaced 24 meV apart. This energy does not correspond to any phonons with high density of states in the diamond crystal. The relative intensities of the main lines exhibit no temperature dependence (between 20 and 160 Ii), implying ground-state splitting. The narrow linewidth and temperature-independent emission energy imply only weak interaction with the diamond host The temperature-dependence of the linewidth is well described by thermal broadening. We attribute the emission to optical centers as a consequence of tungsten incorporation into the diamond film. The tungsten originates from the electrode during deposition.
引用
收藏
页码:13428 / 13431
页数:4
相关论文
共 22 条
[1]  
ANDERSON F, UNPUB
[2]  
ANDERSON RJ, 1996, B AM PHYS SOC, V41, P438
[3]   THE ORIGIN OF THE BROAD-BAND LUMINESCENCE AND THE EFFECT OF NITROGEN DOPING ON THE OPTICAL-PROPERTIES OF DIAMOND FILMS [J].
BERGMAN, L ;
MCCLURE, MT ;
GLASS, JT ;
NEMANICH, RJ .
JOURNAL OF APPLIED PHYSICS, 1994, 76 (05) :3020-3027
[4]  
BERGMAN L, 1994, MATER RES SOC S P, V339, P664
[5]   PHOTOLUMINESCENCE ASSOCIATED WITH 1.673, 1.944 AND 2.498 EV CENTRES IN DIAMOND [J].
CLARK, CD ;
NORRIS, CA .
JOURNAL OF PHYSICS PART C SOLID STATE PHYSICS, 1971, 4 (14) :2223-&
[6]   RAMAN AND PHOTOLUMINESCENCE SPECTRA OF AS-GROWN CVD DIAMOND FILMS [J].
CLARK, CD ;
DICKERSON, CB .
JOURNAL OF PHYSICS-CONDENSED MATTER, 1992, 4 (03) :869-878
[7]   A SPECTROSCOPIC STUDY OF OPTICAL-CENTERS IN DIAMOND GROWN BY MICROWAVE-ASSISTED CHEMICAL VAPOR-DEPOSITION [J].
COLLINS, AT ;
KAMO, M ;
SATO, Y .
JOURNAL OF MATERIALS RESEARCH, 1990, 5 (11) :2507-2514
[8]  
DALLAS T, 1995, APPL DIAMOND FILMS R, P449
[9]   OPTICAL STUDIES OF 1.945 EV VIBRONIC BAND IN DIAMOND [J].
DAVIES, G ;
HAMER, MF .
PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1976, 348 (1653) :285-298
[10]   CHARACTERISTICS AND ORIGIN OF THE 1.681 EV LUMINESCENCE CENTER IN CHEMICAL-VAPOR-DEPOSITED DIAMOND FILMS [J].
FENG, T ;
SCHWARTZ, BD .
JOURNAL OF APPLIED PHYSICS, 1993, 73 (03) :1415-1425