A Tetrathiafulvalene (TTF)-Conjugated Microporous Polymer Network

被引：47

作者：

Bildirir, Hakan ^{[1
]}

Paraknowitsch, Jens Peter ^{[1
]}

Thomas, Arne ^{[1
]}

机构：

[1] Tech Univ Berlin, Dept Chem, D-10623 Berlin, Germany

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2014年 / 20卷 / 31期

基金：

欧洲研究理事会;

关键词：

donor-acceptor polymers; microporous polymers; organic electronics; post-synthetic modification; tetrathiafulvalene; COVALENT ORGANIC FRAMEWORKS; TRIAZINE-BASED FRAMEWORKS; HETEROGENEOUS CATALYSIS; POROUS POLYIMIDES; HYDROGEN STORAGE; ELECTRON-DONORS; CHARGE-TRANSFER; CARBON-DIOXIDE; TTF; FILMS;

D O I：

10.1002/chem.201402278

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Conjugated microporous polymer networks have been prepared from the strong electron donor tetrathiafulvalene (TTF) and 1,3,5-triethynylbenzene (TEB) by using the Sonogashira-Hagihara cross-coupling reaction. Optimization of reaction conditions yields polymers with surface areas of up to 434 m(2)g(-1). The strong electron-donating properties of the network can be proven by iodine exposure. Structural and electronic changes due to formation of the charge-transfer salt from TTFs in the porous network and iodine within the pores are investigated.

引用

页码：9543 / 9548

页数：6

共 79 条

[1] [Anonymous], 2007, ANGEW CHEM INT ED, V46, P8574
[2] [Anonymous], ANGEW CHEM
[3] [Anonymous], 2010, ANGEW CHEM INT ED, V49, P8328
[4] [Anonymous], 1995, Handbook of X-ray Photoelectron Spectroscopy. A Reference Book of Standard Spectra for Identification and Interpretation of XPS Data
[5] [Anonymous], 2013, ANGEW CHEM INT ED, V52, P12174
[6] [Anonymous], 2013, ANGEW CHEM INT ED, V52, P2920
[7] [Anonymous], 2013, ANGEW CHEM, V125, P12396
[8] [Anonymous], 2012, ANGEW CHEM INT ED, V51, P5456
[9] [Anonymous], 2008, ANGEW CHEM INT ED, V47, P3450
[10] COMPARATIVE-STUDY OF THE ELECTRONIC-STRUCTURE AND CONDUCTION PROPERTIES OF POLYPYRROLE, POLYTHIOPHENE, AND POLYFURAN AND THEIR COPOLYMERS
BAKHSHI, AK
LADIK, J
SEEL, M
[J]. PHYSICAL REVIEW B, 1987, 35 (02): : 704 - 712

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