The effects of cis-trans configuration of cyclohexane multi-carboxylic acids on colloidal forces in dispersions: steric, hydrophobic and bridging

被引:10
作者
Chandramalar, AVM
Lim, YY
Leong, YK
机构
[1] Ngee Ann Polytech, Dept Biotechnol, Singapore 599489, Singapore
[2] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
关键词
steric; bridging; hydrophobic forces; yield stress; pH; dispersions; cyclohexane; carboxylic acids;
D O I
10.1016/S0927-7757(99)00028-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The effects of cis- and trans-1,2, trans-1,4-cyclohexanedicarboxylic acid, 95% cis-1,3,5-cyclohexane tricarboxylic acid and cis-l,2,3,4,5,6-cyclohexanehexacarboxylic acid on the yield stress-pH behaviour of concentrated ZrO2 dispersions are reported. Adsorbed cis-1,2,3,4,5,6-cyclohexanehexacarboxylic acid imparts predominantly steric interactions. It forms a steric barrier keeping the interacting particles apart. Adsorbed cis- and trans-1,2 increase the maximum yield stress and this was attributed to a hydrophobic force resulting from the part of the cyclohexane ring sticking out into the solution which is devoid of charged or hydrophilic group. Adsorbed trans-1,4 increases the maximum yield stress by at least threefold and its configuration favours strong bridging interaction with an adjacent particle. Predominantly, cis-1,3,5 also increases the maximum yield stress but only by 60% at the same additive concentration. This was attributed to a smaller degree of bridging. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:199 / 205
页数:7
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