Supramolecular chirogenesis in bis-porphyrins: Interaction with chiral acids and application for the absolute configuration assignment

被引：31

作者：

Bhyrappa, Puttaiah ^{[1
]}

Borovkov, Victor V. ^{[1
]}

Inoue, Yoshihisa ^{[1
]}

机构：

[1] JST, ICORP, Entropy Control Project, Toyonaka, Osaka 5600085, Japan

来源：

ORGANIC LETTERS | 2007年 / 9卷 / 03期

关键词：

D O I：

10.1021/ol062776w

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new supramolecular chirogenic system on the basis of bis(free base porphyrin) and various enantiopure acids, which can be effectively applied for the chirality sensing purposes, is reported. The temperature and solvent are found to be key factors controlling the chirality transfer process in these assemblies.

引用

页码：433 / 435

页数：3

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