Carbon dioxide utilisation in the chemical industry.

被引:40
作者
Aresta, M
Tommasi, I
机构
关键词
carbon dioxide utilisation; thermodynamics; economics; life cycle assessment;
D O I
10.1016/S0196-8904(96)00297-X
中图分类号
O414.1 [热力学];
学科分类号
摘要
The amount of carbon dioxide available for industrial utilisation may expand to unprecedented levels if the recovery of carbon dioxide from energy plants flue gases will be implemented. The potential of each of the three possible uses (technological, chemical, and biological) is far from being clearly defined. The chemical utilisation option, that has intrinsic thermodynamic and kinetic constraints, may rise controversial positions, depending on the criteria used for the analysis. The estimate of its real potential demands a thorough comparative analysis, using the Life Cycle Assessment methodology, of existing processes/products with the new ones based on CO2, in order to establish whether, or not, the latter avoid carbon dioxide (either directly or indirectly) and their economics. The rejection/consideration assessment methodology will produce reliable results only if an exhaustive number of parameters is used. The analysis cannot be limited to practiced industrial processes, but must be extended to an exhaustive inventory of cases. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:S373 / S378
页数:6
相关论文
共 21 条
[1]   NEW NICKEL-CARBON DIOXIDE COMPLEX - SYNTHESIS, PROPERTIES, AND CRYSTALLOGRAPHIC CHARACTERIZATION OF (CARBON DIOXIDE)-BIS(TRICYCLOHEXYLPHOSPHINE)NICKEL [J].
ARESTA, M ;
NOBILE, CF ;
ALBANO, VG ;
FORNI, E ;
MANASSERO, M .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1975, (15) :636-637
[2]   BIOMIMETIC BUILDING-UP OF THE CARBAMIC MOIETY - THE INTERMEDIACY OF CARBOXYPHOSPHATE ANALOGS IN THE SYNTHESIS OF N-ARYL CARBAMATE ESTERS FROM ARYLAMINES AND ORGANIC CARBONATES PROMOTED BY PHOSPHORUS-ACIDS [J].
ARESTA, M ;
BERLOCO, C ;
QUARANTA, E .
TETRAHEDRON, 1995, 51 (29) :8073-8088
[3]   ROLE OF THE MACROCYCLIC POLYETHER IN THE SYNTHESIS OF N-ALKYLCARBAMATE ESTERS FROM PRIMARY AMINES, CO2 AND ALKYL-HALIDES IN THE PRESENCE OF CROWN-ETHERS [J].
ARESTA, M ;
QUARANTA, E .
TETRAHEDRON, 1992, 48 (08) :1515-1530
[4]   PROSPECTS FOR THE UTILIZATION OF CARBON-DIOXIDE [J].
ARESTA, M ;
QUARANTA, E ;
TOMMASI, I .
ENERGY CONVERSION AND MANAGEMENT, 1992, 33 (5-8) :495-504
[5]   THE FIXATION OF CARBON-DIOXIDE IN INORGANIC AND ORGANIC-CHEMICALS [J].
ARESTA, M .
ENERGY CONVERSION AND MANAGEMENT, 1993, 34 (9-11) :745-752
[6]  
ARESTA M, 1994, NEW J CHEM, V18, P133
[7]   Mechanism of formation of peroxocarbonates RhOOC(O)O(Cl)(P)(3) and their reactivity as oxygen transfer agents mimicking monooxygenases. The first evidence of CO2 insertion into the O-O bond of Rh(eta(2)-O-2) complexes [J].
Aresta, M ;
Tommasi, I ;
Quaranta, E ;
Fragale, C ;
Mascetti, J ;
Tranquille, M ;
Galan, F ;
Fouassier, M .
INORGANIC CHEMISTRY, 1996, 35 (14) :4254-4260
[8]  
ARESTA M, 1990, NATO ADV SCI I C-MAT, V314, P1
[9]  
ARESTA M, 1993, Patent No. 1237208
[10]  
ARESTA M, 1987, CARBON DIOXIDE SOURC, P1