Extraordinary synergy in the mechanical properties of polymer matrix composites reinforced with 2 nanocarbons

被引:240
作者
Prasad, K. Eswar [3 ]
Das, Barun [1 ,2 ,4 ]
Maitra, Urmimala [1 ,2 ]
Ramamurty, Upadrasta [3 ,5 ]
Rao, C. N. R. [1 ,2 ,4 ,5 ]
机构
[1] Jawaharlal Nehru Ctr Adv Sci Res, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India
[2] Jawaharlal Nehru Ctr Adv Sci Res, CSIR, Ctr Excellence Chem, Bangalore 560064, Karnataka, India
[3] Indian Inst Sci, Dept Mat Engn, Bangalore 560012, Karnataka, India
[4] Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India
[5] Jawaharlal Nehru Ctr Adv Sci Res, Int Ctr Mat Sci, Bangalore 560064, Karnataka, India
关键词
binary combinations; nanoindentation technique; polyvinyl alcohol; synergistic effects; NONCOVALENT FUNCTIONALIZATION; CARBON; NANOCOMPOSITES; SOLUBILIZATION; NANODIAMOND; COVALENT; GRAPHENE; LOAD;
D O I
10.1073/pnas.0905844106
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
One of the applications of nanomaterials is as reinforcements in composites, wherein small additions of nanomaterials lead to large enhancements in mechanical properties. There have been extensive studies in the literature on composites where a polymer matrix is reinforced by a single nanomaterial such as carbon nanotubes. In this article, we examine the significant synergistic effects observed when 2 different types of nanocarbons are incorporated in a polymer matrix. Thus, binary combinations of nanodiamond, few-layer graphene, and single-walled nanotubes have been used to reinforce polyvinyl alcohol. The mechanical properties of the resulting composites, evaluated by the nanoindentation technique, show extraordinary synergy, improving the stiffness and hardness by as much as 400% compared to those obtained with single nanocarbon reinforcements. These results suggest a way of designing advanced materials with extraordinary mechanical properties by incorporating small amounts of 2 nanomaterials such as graphene plus nanodiamond or nanodiamond plus carbon nanotube.
引用
收藏
页码:13186 / 13189
页数:4
相关论文
共 17 条
[1]   Nanodiamond-Polymer Composite Fibers and Coatings [J].
Behler, Kristopher D. ;
Stravato, Antonella ;
Mochalin, Vadym ;
Korneva, Guzeliya ;
Yushin, Gleb ;
Gogotsi, Yury .
ACS NANO, 2009, 3 (02) :363-369
[2]   Morphological and mechanical properties of carbon-nanotube-reinforced semicrystalline and amorphous polymer composites [J].
Cadek, M ;
Coleman, JN ;
Barron, V ;
Hedicke, K ;
Blau, WJ .
APPLIED PHYSICS LETTERS, 2002, 81 (27) :5123-5125
[3]   Nano-indentation studies on polymer matrix composites reinforced by few-layer graphene [J].
Das, Barun ;
Prasad, K. Eswar ;
Ramamurty, U. ;
Rao, C. N. R. .
NANOTECHNOLOGY, 2009, 20 (12)
[4]   Nanomechanical characterization of single-walled carbon nanotube reinforced epoxy composites [J].
Li, XD ;
Gao, HS ;
Scrivens, WA ;
Fei, DL ;
Xu, XY ;
Sutton, MA ;
Reynolds, AP ;
Myrick, ML .
NANOTECHNOLOGY, 2004, 15 (11) :1416-1423
[5]   Mechanical properties of functionalized single-walled carbon-nanotube/poly(vinyl alcohol) nanocomposites [J].
Liu, LQ ;
Barber, AH ;
Nuriel, S ;
Wagner, HD .
ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (06) :975-980
[6]   Covalent and noncovalent functionalisation and solubilisation of nanodiamond [J].
Maitra, Urmimala ;
Gomathi, A. ;
Rao, C. N. R. .
JOURNAL OF EXPERIMENTAL NANOSCIENCE, 2008, 3 (04) :271-278
[7]   AN IMPROVED TECHNIQUE FOR DETERMINING HARDNESS AND ELASTIC-MODULUS USING LOAD AND DISPLACEMENT SENSING INDENTATION EXPERIMENTS [J].
OLIVER, WC ;
PHARR, GM .
JOURNAL OF MATERIALS RESEARCH, 1992, 7 (06) :1564-1583
[8]   Load transfer and deformation mechanisms in carbon nanotube-polystyrene composites [J].
Qian, D ;
Dickey, EC ;
Andrews, R ;
Rantell, T .
APPLIED PHYSICS LETTERS, 2000, 76 (20) :2868-2870
[9]   Functionalized graphene sheets for polymer nanocomposites [J].
Ramanathan, T. ;
Abdala, A. A. ;
Stankovich, S. ;
Dikin, D. A. ;
Herrera-Alonso, M. ;
Piner, R. D. ;
Adamson, D. H. ;
Schniepp, H. C. ;
Chen, X. ;
Ruoff, R. S. ;
Nguyen, S. T. ;
Aksay, I. A. ;
Prud'homme, R. K. ;
Brinson, L. C. .
NATURE NANOTECHNOLOGY, 2008, 3 (06) :327-331
[10]  
Rao CNR, 2005, RSC NANOSCI NANOTECH, pV