Template ordered open-grid arrays of paired endohedral fullerenes

被引：35

作者：

Deak, David S. ^{[1
]}

Silly, Fabien ^{[1
]}

Porfyrakis, Kyriakos ^{[1
]}

Castell, Martin R. ^{[1
]}

机构：

[1] Univ Oxford, Dept Mat, Oxford OX1 3PH, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 43期

关键词：

D O I：

10.1021/ja0634369

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Developing useful molecular systems, such as planar networks for novel molecular electronics, requires the ability to control the way molecules assemble at surfaces. Here we report how an oxide crystal surface can be used as a template to controllably order endohedral fullerenes, Er3N@C80, into two-dimensional (2D) open-grid arrays. The crystal surface is made of highly ordered oxide nanostructures which self-assemble on the surface of SrTiO3(001). This method of molecular ordering can be applied to other fullerenes and has the potential to provide a basis for developing a wide range of molecular architectures. Copyright © 2006 American Chemical Society.

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页码：13976 / 13977

页数：2

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