Synthesis of diruthenium complexes containing chiral thiolate-bridged ligands and their application to catalytic propargylic alkylation of propargylic alcohols with acetone

被引：75

作者：

Nishibayashi, Y

Onodera, G

Inada, Y

Hidai, M

Uemura, S ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Sakyo Ku, Kyoto 6068501, Japan

[2] Sci Univ Tokyo, Fac Ind Sci & Technol, Dept Mat Sci & Technol, Noda, Chiba 2588510, Japan

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 04期

关键词：

D O I：

10.1021/om020814j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel diruthenium complexes containing chiral thiolate-bridged ligands are synthesized and characterized crystallographically. The chiral diruthenium complexes promote enantioselective propargylic alkylation of propargylic, alcohols with acetone to give the corresponding propargylic alkylated products in good yields with moderate enantioselectivities (up to 35% ee).

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页码：873 / 876

页数：4

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