Photocatalytic Splitting of Water Over a Novel Visible-Light-Response Photocatalyst Nd2InTaO7

被引:22
作者
Tang, Xinde [1 ]
Ye, Hongqi [1 ]
Zhao, Zhi [1 ]
Liu, Hui [1 ,2 ]
Ma, Chenxia [1 ]
机构
[1] Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Peoples R China
[2] Cent S Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China
基金
中国博士后科学基金;
关键词
Photocatalysis; Visible-light-response; Water splitting; Pyrochlore-type structure; Lattice distortion; PHOTOPHYSICAL PROPERTIES; D(10) CONFIGURATION; RARE-EARTH; IRRADIATION; DECOMPOSITION; HYDROGEN; OXIDES; O-2; H-2; BI2INNBO7;
D O I
10.1007/s10562-009-0178-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new visible-light-response photocatalyst Nd2InTaO7 with pyrochlore-type structure crystallized in a cubic system with the space group Fd3m was synthesized by a solid-state reaction method. The H-2 evolution was obtained from Pt/CH3OH/H2O solution and pure H2O, and O-2 evolution was generated from an aqueous AgNO3 solution under visible light irradiation (lambda > 400 nm). The high photocatalytic performance of Nd2InTaO7 supported the existing view that the photocatalytic activity correlated with the lattice distortion.
引用
收藏
页码:362 / 369
页数:8
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