The nitration of arenes in perfluorocarbon solvents

被引：17

作者：

Crampton, MR

Cropper, EL

Gibbons, LM

Millar, RW

机构：

[1] Univ Durham, Dept Chem, Durham DH1 3LE, England

[2] QinetiQ Ltd, Sevenoaks TN14 7BP, Kent, England

来源：

GREEN CHEMISTRY | 2002年 / 4卷 / 03期

关键词：

D O I：

10.1039/b200627h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Perfluorocarbons have been used effectively as solvents and bulking agents in the reactions of toluene, benzene, phenol, benzyl chloride and chlorobenzene with nitric acid or dinitrogen pentoxide to yield highly nitrated products. Reactions are carried out in a single stage, at lower temperatures, and producing smaller amounts of waste acid than in traditional processes.

引用

收藏

页码：275 / 278

页数：4

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