Optimization of the electrodeposition of Raney nickel on titanium substrate

被引：10

作者：

Cooper, Matthew ^{[1
]}

Botte, Gerardine G. ^{[1
]}

机构：

[1] Ohio Univ, Dept Chem Engn, Stocker Ctr 183, Athens, OH 45701 USA

来源：

JOURNAL OF MATERIALS SCIENCE | 2006年 / 41卷 / 17期

关键词：

D O I：

10.1007/s10853-006-0317-z

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The electrodeposition of Raney nickel onto a titanium grid substrate was investigated. Optimization of current density and charge density was performed via a factorial design experimental method to maximize the percentage of Raney nickel powder deposited on the grid. A scale-up of the deposition process was performed to demonstrate the feasibility of the procedure using larger substrates. Reproducible electrodes were obtained which can find applications in fuel cells as well as electrolytic hydrogen generators.

引用

页码：5608 / 5612

页数：5

共 13 条

[1] ELECTROCATALYTIC PERFORMANCE OF COMPOSITE-COATED ELECTRODES FOR ALKALINE WATER ELECTROLYSIS [J].

CHOQUETTE, Y ;

MENARD, H ;

BROSSARD, L .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 1990, 15 (01) :21-26

[2] THE COELECTRODE POSITION OF RANEY-NICKEL ALLOY POWDER ON A STAINLESS-STEEL GRID [J].

DANG, A ;

CAPUANO, GA ;

CHAPUZET, JM ;

LESSARD, J .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 1993, 18 (11) :941-944

[3] Characterisation and behaviour of Ti/TiO2/noble metal anodes [J].

de Mussy, JPG ;

Macpherson, JV ;

Delplancke, JL .

ELECTROCHIMICA ACTA, 2003, 48 (09) :1131-1141

[4]

FILARDO G, 1983, J APPL ELECTROCHEM, V13, P403, DOI 10.1007/BF00617514

[5] Electrodeposition of Mackinawite films on Ti:: effects of the S2O32-/Fe2+ mole ratio in the solution [J].

Gomes, A ;

Pereira, MIS ;

Mendonça, MH ;

Costa, FM .

ELECTROCHIMICA ACTA, 2004, 49 (13) :2155-2165

[6]

LARMINIE J, 2003, FUEL CELL SYSTEMS EX, P135

[7]

LOCHNER RH, 1990, DESIGNING QUALITY, P26

[8] PREPARATION AND USE OF RANEY-NI ACTIVATED CATHODES FOR LARGE-SCALE HYDROGEN-PRODUCTION [J].

LOHRBERG, K ;

KOHL, P .

ELECTROCHIMICA ACTA, 1984, 29 (11) :1557-1561

[9]

LOS P, 1993, J APPL ELECTROCHEM, V23, P135

[10] Performance of supercapacitor with electrodepo sited ruthenium oxide film electrodes - Effect of film thickness [J].

Park, BO ;

Lokhande, CD ;

Park, HS ;

Jung, KD ;

Joo, OS .

JOURNAL OF POWER SOURCES, 2004, 134 (01) :148-152

← 1 2 →