Stereoselective synthesis of triterpene 2-deoxy-alpha-D-lyxo-hexopyranosides

被引：3

作者：

Baltina, LA ^{[1
]}

Flekhter, OB ^{[1
]}

Vasileva, EV ^{[1
]}

Tolstikov, GA ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,INST ORGAN CHEM,UFA 450054,RUSSIA

来源：

RUSSIAN CHEMICAL BULLETIN | 1997年 / 46卷 / 03期

基金：

俄罗斯基础研究基金会;

关键词：

glycyrrhetic acid; allobetulin; D-galactal acetates; N-iodosuccinimide; 2-deoxy-2-iodo-alpha-D-talopyranosides; 2-deoxy-alpha-D-lyxo-hexopyranosides;

D O I：

10.1007/BF02495418

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2-Deoxy-alpha-D-lyxo-hexopyranosides of 18 beta-glycyrrhetic acid, its 11-deoxo derivative and allobetulin were synthesized by glycosylation of oleonane-type triterpene alcohols with D-galactal acetate in the presence of N-iodosuccinimide followed by deiodination and deprotection.

引用

页码：577 / 581

页数：5

共 17 条

[1]

BALTINA LA, 1995, MENDELEEV COMMUN, P178

[2]

Baltina LA, 1996, MENDELEEV COMMUN, P63

[3] Stereoselective synthesis of 2-deoxy-alpha-D-arabino-hexopyranosides of triterpene alcohols [J].