Terpenic olefin epoxidation using metals acetylacetonates as catalysts

被引：43

作者：

Fdil, N

Romane, A

Allaoud, S

Karim, A

Castanet, Y

Mortreux, A

机构：

[1] UNIV CADI AYYAD,FAC SCI SEMLALIA,CHIM COORDINAT LAB,MARRAKECH,MOROCCO

[2] ENSC LILLE,URA CNRS 402,CATALYSE HETEROGENE & HOMOGENE LAB,F-59652 VILLENEUVE DASCQ,FRANCE

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1996年 / 108卷 / 01期

关键词：

epoxidation; nickel; acetylacetonate; transition metals; terpenic olefins; oxygen;

D O I：

10.1016/1381-1169(95)00284-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Efficient epoxidation of natural terpenic olefins is performed using nickel acetylacetonate, oxygen and a branched aldehyde at ambient temperature. Total conversions are achieved with selectivities up to 90% into epoxide. Under the same conditions other catalytic systems using transition metal acetylacetonates (M(n)(acac)(n)) have been used, some of which also gave satisfactory results.

引用

收藏

页码：15 / 21

页数：7

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