A simple synthesis of metallic Ni and Ni-Co alloy fine powders from a mixed-metal acetate precursor

被引：60

作者：

Syukri ^{[1
]}

Ban, T ^{[1
]}

Ohya, Y ^{[1
]}

Takahashi, Y ^{[1
]}

机构：

[1] Gifu Univ, Fac Engn, Dept Appl Chem, Gifu 5011193, Japan

来源：

MATERIALS CHEMISTRY AND PHYSICS | 2003年 / 78卷 / 03期

关键词：

metal acetate; nanoparticles; nickel;

D O I：

10.1016/S0254-0584(02)00185-2

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A new process for the synthesis of metallic Ni, and Ni-Co alloy nanoparticles at a relatively low temperature is reported. The process consists of heating a precursor containing a methyl hydrazine complex of the respective metal ions in nitrogen atmosphere at temperature as low as 400degreesC. The metallic Ni and Ni-Co alloy powders are characterized by scanning electron microscopy, powder X-ray diffraction (XRD), differential thermal analysis (DTA), and thermogravimetric (TG) analysis. The crystalline nanoparticles showed a narrow distribution in the particle size and homogeneous spherical form with mean diameter around 0.40 mum. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：645 / 649

页数：5

共 20 条

[1] Production of Co-Ni alloys by mechanical-alloying [J].

Aymard, L ;

Dumont, B ;

Viau, G .

JOURNAL OF ALLOYS AND COMPOUNDS, 1996, 242 (1-2) :108-113

[2] Novel nickel catalysts based on perfluoroalkyl-β-diketone ligands for the selective dimerization of propylene to 2,3-dimethylbutenes [J].

Benvenuti, F ;

Carlini, C ;

Marchetti, F ;

Marchionna, M ;

Galletti, AMR ;

Sbrana, G .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 622 (1-2) :286-292

[3] HEXAGONAL CLOSE PACKED NICKEL POWDER - SYNTHESIS, STRUCTURAL CHARACTERIZATION AND THERMAL-BEHAVIOR [J].

CARTURAN, G ;

COCCO, G ;

ENZO, S ;

GANZERLA, R ;

LENARDA, M .

MATERIALS LETTERS, 1988, 7 (1-2) :47-50

[4] Preparation of dense spherical Ni particles and hollow NiO particles by spray pyrolysis [J].

Che, SL ;

Takada, K ;

Takashima, K ;

Sakurai, O ;

Shinozaki, K ;

Mizutani, N .

JOURNAL OF MATERIALS SCIENCE, 1999, 34 (06) :1313-1318

[5] Synthesis of nickel nanoparticles in water-in-oil microemulsions [J].

Chen, DH ;

Wu, SH .

CHEMISTRY OF MATERIALS, 2000, 12 (05) :1354-1360

[6] Preparation of submicrometer nickel powders by the reduction from nonaqueous media [J].

Degen, A ;

Macek, J .

NANOSTRUCTURED MATERIALS, 1999, 12 (1-4) :225-228

[7] The oxidative chemistry of methane over supported nickel catalysts [J].

Diskin, AM ;

Cunningham, RH ;

Ormerod, RMZ .

CATALYSIS TODAY, 1998, 46 (2-3) :147-154

[8] Surface characterizations of ultrafine Ni particles [J].

Dong, XL ;

Zhang, ZD ;

Jin, SR ;

Sun, WM ;

Chuang, YC .

NANOSTRUCTURED MATERIALS, 1998, 10 (04) :585-592

[9] HOMOGENEOUS AND HETEROGENEOUS NUCLEATIONS IN THE POLYOL PROCESS FOR THE PREPARATION OF MICRON AND SUB-MICRON SIZE METAL PARTICLES [J].

FIEVET, F ;

LAGIER, JP ;

BLIN, B ;

BEAUDOIN, B ;

FIGLARZ, M .

SOLID STATE IONICS, 1989, 32-3 :198-205

[10] SYNTHESIS AND CHARACTERIZATION OF ANISOMETRIC COBALT NANOCLUSTERS [J].

GIBSON, CP ;

PUTZER, KJ .

SCIENCE, 1995, 267 (5202) :1338-1340

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