Origin of the asymmetric induction in metallosalen-catalyzed reactions of aldehydes

被引：4

作者：

Chaladaj, Wojciech ^{[1
]}

Jurczak, Janusz ^{[1
,2
]}

机构：

[1] Polish Acad Sci, Inst Organ Chem, PL-01224 Warsaw, Poland

[2] Warsaw Univ, Dept Chem, PL-02093 Warsaw, Poland

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 44期

关键词：

DIELS-ALDER REACTIONS; JACOBSEN-KATSUKI EPOXIDATION; CHIRAL (SALEN)CHROMIUM(III) COMPLEXES; (SALEN)MANGANESE(III) COMPLEX; DFT; COORDINATION; ENHANCEMENT; ALKENES; OLEFINS; DESIGN;

D O I：

10.1039/b910473a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This study investigates, experimentally and computationally, the role played by the structure of the diamine moiety of salen chromium complexes in determining the catalyst conformational equilibrium and, in consequence, the direction of asymmetric induction in metallosalen-catalyzed reactions of aldehydes.

引用

页码：6747 / 6749

页数：3

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